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Cyclopropane anisotropy. Effects of systematically varied cyclopropane geometries in aromatic systems

โœ Scribed by Hahn, Roger C.; Howard, Philip H.


Book ID
127119061
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
794 KB
Volume
94
Category
Article
ISSN
0002-7863

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ChemInform Abstract: Directing Effect of
โœ J. COSSY; N. BLANCHARD; C. MEYER ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 33 KB ๐Ÿ‘ 2 views

Directing Effect of a Neighboring Aromatic Group in the Cyclopropanation of Allylic Alcohols. -Various racemic allylic alcohols are stereoselectively transformed to cyclopropanes with I-CH 2 -Cl in the presence of either zinc or samarium reagent. Alcohols bearing an aryl group at the stereocenter a