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Cyclopropanation reactions with α, β-epoxy diazomethyl ketones and rearrangement of α, β-epoxy cyclopropyl ketones

✍ Scribed by F.L.M. Smeets; L. Thijs; B. Zwanenburg


Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
396 KB
Volume
36
Category
Article
ISSN
0040-4020

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Rearrangement and cyclization reactions
✍ A.C. Brouwer; L. Thijs; B. Zwanenburg 📂 Article 📅 1975 🏛 Elsevier Science 🌐 French ⚖ 224 KB

a.B-Epoxy diazomethyl ketones, a class of compounds that recently became a-vailable1'2, possess two functional groups sensitive to acidic reagents. In a previous paper' we showed that with proton acids the primary reaction takes place at the diazomethyl ketone moiety, e.g. hydrogen chloride in ether