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Cyclophans. 12. [2.2](1,4)tropylio(1,4)cycloheptatrienophane tetrafluoroborate. synthesis and charge-transfer interaction

โœ Scribed by Joseph G. O'Connor; Philip M. Keehn

Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
191 KB
Volume
18
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

wolecular charge-transfer complexes are of great interest both theoretically and practically.3 Recently however strong emphasis is being placed on studies involving intramolecular charge-transfer complexes. 4 These systems are of interest because of the potential they have as novel materials for organic semiconductors and because they are excellent models for the study of charge-transfer processes. 3b,d Unlike their intermolecular counterparts, intramolecular charge transfer complexes with a fixed orientation of donor and acceptor, are non-dissociable. The forced proximity not only prevents dissociation of donor-acceptor pairs

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