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Cyclopentane synthesis and annulation: Intramolecular radical cyclization of acetals

✍ Scribed by Veejendra K. Yadav; Alex G. Fallis

Publisher: Elsevier Science
Year: 1988
Tongue: French
Weight: 232 KB
Volume: 29
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)82476-4

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✦ Synopsis

A general procedure for cyclopentane synthesis based on free-radical cyclization of thioacetals is described.

This permits the rapid assembly, by intramolecular annulation, of various ring systems bearing useful functionality for use in total synthesis.

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