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CYCLOPENTADIENYL COMPOUNDS OF Sc, Y, La, Ce AND SOME LANTHANIDE ELEMENTS

✍ Scribed by Wilkinson, G.; Birmingham, J. M.

Book ID: 119966216
Publisher: American Chemical Society
Year: 1954
Tongue: English
Weight: 149 KB
Volume: 76
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja01652a114

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## Abstract Quasi‐relativistic Douglas–Kroll CASPT2 calculations are reported for the title molecules, mainly to provide primary data for a fit of double‐bond covalent radii. Indeed, a well‐developed σ^2^π^2^ double bond is identified in all cases. For Eu and Yb, however, it is an excited state. Th