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Cyclometallation of 2-(2-thienyl)pyridine and 2-(3-thienyl)pyridine with palladium(II), rhodium(III) and ruthenium(II)

✍ Scribed by Matsuo Nonoyama; Sachiyo Kajita


Publisher
Springer
Year
1981
Tongue
English
Weight
272 KB
Volume
6
Category
Article
ISSN
0340-4285

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Pyridine- and 3-/6-Methylpyridine-2-tell
✍ Sandip Dey; VimalΒ K. Jain; Jaspreet Singh; Veena Trehan; KuldipΒ K. Bhasin; Babu πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 153 KB

## Abstract The reaction of py~2~Te~2~ or (3‐MeC~5~H~3~N)~2~Te~2~ with Na~2~PdCl~4~ in methanol yields an insoluble brown complex, [PdCl(TeNC~5~H~3~R)]~__n__~ (R = H or Me). Several reactions of pyTe^βˆ’^, (3‐MeC~5~H~3~N)Te^βˆ’^, or (6‐MeC~5~H~3~N)Te^βˆ’^ with various palladium(II) and platinum(II) compl