Cyclometallated derivatives of palladium(II) and platinum(II) derived from 6-t-butyl-2,2′-bipyridine
✍ Scribed by Sergio Stoccoro; Giorgio Chelucci; Maria Agostina Cinellu; Antonio Zucca; Giovanni Minghetti
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 182 KB
- Volume
- 450
- Category
- Article
- ISSN
- 0022-328X
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## Abstract A series of luminescent cyclometalated platinum (II) complexes, (CNN)Pt(CC̊) [HCNN = 4‐(4‐tolyl)‐6‐phenyl‐2,2′‐bipyridine; R = 4‐chlorophenyl (1), phenyl (2) and 4‐tolyl (3)], were synthesized, and their spectroscopic properties have been examined. These complexes are brightly emissive
## Abstract The reaction of py~2~Te~2~ or (3‐MeC~5~H~3~N)~2~Te~2~ with Na~2~PdCl~4~ in methanol yields an insoluble brown complex, [PdCl(TeNC~5~H~3~R)]~__n__~ (R = H or Me). Several reactions of pyTe^−^, (3‐MeC~5~H~3~N)Te^−^, or (6‐MeC~5~H~3~N)Te^−^ with various palladium(II) and platinum(II) compl