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Cyclometalated rhodium complexes of phenyl- and diphenyl-substituted oxazole and thiazole luminophores

✍ Scribed by Katlenok, E. A.; Balashev, K. P.


Book ID
118725598
Publisher
Springer
Year
2012
Tongue
English
Weight
198 KB
Volume
82
Category
Article
ISSN
1070-3632

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Schiff's bases derived from 2-aminothiazole and substituted benzaldehydes were reacted with [RhCI(PPh3)3] or [Rh-(/~-CI)(COD)] 2 (COD = 1,5-cyclooctadiene) in the presence of four equivalents of PPh3 to give Rh m cyclometallated complexes of the type [RhHCI{ (X-benzylidene) thiazole}-(PPh3)2], in wh