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Cyclomagnesiation of nitrogen-containing 1,2-dienes with grignard compounds catalyzed by Cp2TiCl2

✍ Scribed by V. A. D’yakonov; A. A. Makarov; E. Kh. Makarova; L. M. Khalilov; U. M. Dzhemilev


Book ID
114993876
Publisher
SP MAIK Nauka/Interperiodica
Year
2012
Tongue
English
Weight
216 KB
Volume
48
Category
Article
ISSN
1070-4280

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Cp2TiCl2-Catalyzed reaction of grignard
✍ Yongmin Zhang; Jinlong Jiang; Yongqian Chen 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 150 KB

Isocyanates react with isopropyl or set-butylmagnesium bromide in the presence of a small amount of Cp2TiCl to afford amide5 with normal alkyl group. A possibl mechanism for this reac 3 ion is proposed. Cp2TiC12 has recently received more and more attention in organic synthesis. ## Sato and his c