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Cyclohexyne Cycloinsertion by an Annulative Ring Expansion Cascade

✍ Scribed by Christian M. Gampe; Samy Boulos; Erick M. Carreira

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
358 KB
Volume
49
Category
Article
ISSN
0044-8249

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## Abstract The intramolecular iron‐catalyzed ring expansion reaction of epoxyalkenes was investigated with a preformed iron(salen) [Fe(Salen)] complex. The formal insertion of the alkene into the epoxide generated hexahydrocyclopenta[__c__]furan derivatives in moderate to good yields and diastereo