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Cyclo­hexane-1,4-diammonium tetra­hydroxotetra­borate 2.5-hydrate

✍ Scribed by Pan, Chun-Yang ;Wang, Guo-Ming ;Zheng, Shou-Tian ;Yang, Guo-Yu


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
160 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title compound, [C~6~H~10~(NH~3~)~2~]^2+^·[B~4~O~5~(OH)~4~]^2−^·2.5H~2~O, the asymmetric unit contains one anion, two half-cations and 2.5 water molecules. Each cation is centrosymmetric. In the crystal structure, the anions are connected to each other via hydrogen bonding, forming a three-dimensional framework with rectangular channels, which are occupied by the templating organic amine cations and guest water molecules.


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✍ Elangovan, A. ;Thamaraichelvan, A. ;Ramu, A. ;Athimoolam, S. ;Natarajan, S. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 499 KB

The asymmetric unit of the title compound, C~8~H~22~N~2~ ^2+^·2C~7~H~6~NO~2~ ^−^·2.25H~2~O, consists of half each of two centrosymmetric tetramethylbutane-1,4-diammonium cations, two __p__-aminobenzoate anions and 2.25 solvent water molecules. As a characteristic feature of 4-aminocarboxylic acid, t