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Cyclohexa-3,5-diene-1,2-trans-diols – Synthesis and Application in Target-Oriented Syntheses

✍ Scribed by Tobias Hausmann; Jörg Pietruszka; Sebastian Schumacher


Book ID
111992720
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
836 KB
Volume
354
Category
Article
ISSN
1615-4150

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Chemical synthesis of optically active c
✍ Takeshi Hanazawa; Sentaro Okamoto; Fumie Sato 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 64 KB

A variety of optically active 3-substituted cis-cyclohexane-3,5-dien-1,2-diol acetonides were readily prepared from chiral 5-(tert-butyldimethylsilyloxy)-2-cyclohexenone through a seven-step reaction in good overall yield. The synthesis also allowed preparation of the acetonide having an 2 H-atom at