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Cyclodimerization of 3,2-Stevens rearrangement products of 1,9-bisammonium salts containing a 5-oxanonane-2,7-diyne-1,9-diyl group

โœ Scribed by M. O. Manukyan; A. V. Babakhanyan; G. A. Panosyan; S. T. Kocharyan

Book ID
111458848
Publisher
Springer
Year
2006
Tongue
English
Weight
59 KB
Volume
76
Category
Article
ISSN
1070-3632

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The transition-metal-carhonyl-induced cyclodimerization of 5,6-dimethylidene-7-oxabicyclo[2.2.l]hept-2-ene is strongly affected by substitution at C( I). While 5,6-dimethylidene-7-oxahicyclo[2.2.l]hept-2-ene-I-methanol (7) refused to undergo [4 + 21-cyclodimerization in the presence of [Fe2(C0)9] in