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Cyclodextrins in polymer synthesis: Steric retardation of the free-radical polymerization in aqueous medium of 4-vinylbenzaldehyde/methylated β-cyclodextrin complex

✍ Scribed by Michael Heinenberg; Helmut Ritter

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
171 KB
Volume
203
Category
Article
ISSN
1022-1352

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✍ Julia Jeromin; Helmut Ritter 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 251 KB

The polymerisation mechanism of 2,6-dimethyl-P-cyclodextrin (Me2-P-CD) complexes of phenyl methacrylate (1) and cyclohexyl methacrylate (2) is described. The polymerisation of the complexes l a and 2a was canied out in water with potassium peroxodisulfate/potassium hydrogensulfite as initiator. The