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Cyclodextrins and methylated cyclodextrins as stationary phases in gas-solid chromatography

✍ Scribed by J. Mráz; L. Feltl; E. Smolková-Keulemansová


Book ID
108337832
Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
367 KB
Volume
286
Category
Article
ISSN
1873-3778

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Cyclodextrins as stationary phases in ch
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4] Ahbrei izlion for ~'-cyclopentadienyl-(3,4,5,8,9-~'-tricycl0-[5.2.1.0~~]deca-3.X-dien-5-yi)iron. DicpFeCp is used here as an acronym. [S] El-MS (70 eV): m/z (rel. int.) 252 (M", 43), 186 ([M-C,H,,]', loo), 121 (CpFe .65), 56 (Fe', 38).-'H-NMR (ChDhr 270 MHz, 30°C): 6= 1.36 (dt. 'J=8.8 Hz, 'J= 1.

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## Abstract Transferring the site of specific substitution of dipentylated cyclodextrins with methyl or acyl residues from the secondary 3‐hydroxyl group to the primary 6‐hydroxyl group was expected to provide new information on the mechanism of chiral recognition. The 3‐position points towards and