๐”– Bobbio Scriptorium
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Cyclodextrin-Mediated Deacylation of Amino Acid Esters with Marked Stereoselectivity.

โœ Scribed by Koichi Goto; Kentaro Nakashima; Osamu Tanoue; Satoshi Nukushina; Isao Toudo; Chikara Imamura; Yasuji Ihara; Yoko Matsumoto; Ryuichi Ueoka


Publisher
John Wiley and Sons
Year
2003
Weight
96 KB
Volume
34
Category
Article
ISSN
0931-7597

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Alkyne bridged ฮฑ- amino acids by palladi
โœ Bernd Kayser; Janina Altman; Wolfgang Beck ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 432 KB

The Heck reaction of trimethylsilylacetylene with N-t-Boc-4-iodo-L-phenylalanine methyl ester gives N-t-Boc-4-ethynyl-L-phenylalanine methyl ester (2). Coupling of 2 with different alkynes yields alkyne bridged linear amino acid esters 3-5. Also tripodal and tetrapodal amino acid esters 10 and 11 we