𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Cyclocopolymerization of d-limonene with maleic anhydride

✍ Scribed by T. Doiuchi; H. Yamaguchi; Y. Minoura

Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
618 KB
Volume
17
Category
Article
ISSN
0014-3057

No coin nor oath required. For personal study only.

✦ Synopsis

d-Limonene (Lim), a nonconjugated 1,5-diene, was copolymerized with maleic anhydride (MAn) in tetrahydrofuran with ct,ct'-azobisisobutyronitrile as initiator. The composition, spectral analyses, and other physical properties of the resulting copolymer and its hydrolysed product suggest that Lim readily undergoes an inter-intramolecular cyclocopolymerization with MAn, leading to a 1:2 alternating copolymer. The findings and the proposed cyclocopolymerization mechanism are consistent with participation of a charge-transfer complex of the comonomers in the propagation step. The copolymers are optically active and their CD spectra are characterized by dichroic bands attributable to electronic transitions of carbonyl or carboxylic chromophores.

📜 SIMILAR VOLUMES

Optically active polymers, 2. Copolymeri
Optically active polymers, 2. Copolymerization of limonene with maleic anhydride
✍ Jolanta Maślińska-Solich; Teobald Kupka; Mirosław Kluczka; Anton Solich 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 347 KB

## Abstract Copolymerization of maleic anhydride (MA) and (__R__),(__S__)‐limonene (LIM) was studied in various solvents, using 2,2′‐azoisobutyronitrile (AIBN) and benzoyl peroxide (BPO) as initiators and radiation (^60^Co γ‐source) within the temperature range of 20–70°C. Regardless of conversion

Complex-radical cyclocopolymerization of
Complex-radical cyclocopolymerization of allyl a-(N-maleimido)acetate with styrene and maleic anhydride
✍ Zakir M. O. Rzaev; Ulviye U. Salamova; Şemsettin Altindal 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 599 KB

## Abstract Radical copolymerizations of allyl __a__‐(__N__‐maleimido)acetate (AMI) with styrene (__D__, electron‐donor) or maleic anhydride (__A__, electron‐acceptor) were carried out in benzene and/or methyl ethyl ketone (MEK) at 50–70°C in the presence of 2,2′‐azoisobutyronitrile (AIBN) as initi