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Cyclocondensation of 2-Fluoro-5-nitrobenzaldehyde with Amidines. New Synthesis of Isoquinolines.

✍ Scribed by D. V. Dar'in; S. I. Selivanov; P. S. Lobanov; A. A. Potekhin

Publisher
John Wiley and Sons
Year
2005
Weight
26 KB
Volume
36
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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## Abstract The reaction of __N__‐thioamido amidines **1** with tris(dimethylamino)phosphine or bis(diethylamino)phenylphosphine in refluxing toluene leads to the 1,3,5,2Ξ»^3^‐triazaphosphorines **2** and **3**, respectively. The condensation results in the release of two molecules of dialkylamine.