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Cycloaromatization of bridged diallenes: Mechanistic study

โœ Scribed by S. Braverman; Y. Duar

Book ID
104245637
Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
192 KB
Volume
19
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Recently, we have reported on the cycloaromatisation of several bridged diallenic systems, l_, 3, 7. 1 This previous work, -as well as the present one, concern bridged diallenes in which the bridge contributes an aromatic character, and consequently an extra driving force for the cyclization. The methyl substituents give rise to a possibility of an ene reaction , which does not exist in the case of the unsubstituted

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