Cycloadditions of cyanoketenes to cinnamylidenamines and benzylidenamines. Synthetic scope, stereochemistry, and mechanism
✍ Scribed by Moore, Harold W.; Hughes, Gregory; Srinivasachar, Kasturi; Fernandez, Mario; Nguyen, Nghi V.; Schoon, Doug; Tranne, Anne
- Book ID
- 118028007
- Publisher
- American Chemical Society
- Year
- 1985
- Tongue
- English
- Weight
- 951 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0022-3263
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This manuscript describes the regiospecific 1,3-dipolar cycloadditions of 2-aminothioisomu ¨nchnones (1-3) with methyl propiolate. The structure of compound 4 has been unequivocally determined by X-ray crystallography. Based on these experimental arguments and a theoretical rationale that supports t
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