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Cycloadditions of a carbonyl ylide from 2,3-dicyano-2,3-diphenyloxiran

✍ Scribed by Hamberger, Helmut; Huisgen, Rolf


Book ID
115461729
Publisher
Royal Society of Chemistry
Year
1971
Weight
303 KB
Volume
19
Category
Article
ISSN
0577-6171

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β€œTailor-Made” carbonyl ylides: [3 + 2] c
✍ Makoto Hojo; Hidenori Aihara; Hajime Ito; Akira Hosomi πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 French βš– 311 KB

Tailor-made" carbonyl ylides bearing only alkyl substituents or no substituents were efficiently generated from a-chloroalkyl a'-chloroalkyl ethers in the presence of samarium reagents. Using these novel and synthetically practical carbonyl ylides, optionally substituted and stereochemically defmed