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Cycloaddition. XIV. Thermal cycloaddition of trifluoroethylene to some conjugated dienes, and of vinylidene fluoride to butadiene

โœ Scribed by Walker, Leigh E.; Bartlett, Paul D.


Book ID
126193184
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
868 KB
Volume
95
Category
Article
ISSN
0002-7863

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โœ R.G Visser; E.A Oostveen; H.J.T Bos ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 119 KB

Reaction of thioxanthene-9-thione 1 with thealkyl substituted pentatetraenes 2a-g gives mixtures of the thietanes 3a-g and 4a-g. The ratio 3/4 in the thermal reaction is strongly dependent on the sub?tituents:-Ifi the case of 2a thermal rearrangement of the product leads to a stable thiete. \_\_ Du