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Cycloaddition reactions. XIV. Thermal and photochemical reactions of some bicyclic aziridine enol ethers

โœ Scribed by Haddadin, Makhluf J.; Hassner, Alfred

Book ID
120210156
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
895 KB
Volume
38
Category
Article
ISSN
0022-3263

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Thermal and photochemical reactions of u
Thermal and photochemical reactions of unsaturated bicyclic endoperoxides
โœ Howard A.J. Carless; Robert Atkins; G.K. Fekarurhobo ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 254 KB

Thermal, and especially photochemical, rearrangement of the endoperoxides (1) and ( )-( ) gives By-epoxycycloalkanones as primary products, accompanied by the expected syn-diepoxides. Unsaturated endoperoxides [e.g.(l)] are readily available by reaction of singlet oxygen ('0,) with conjugated diene