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Cycloaddition reactions to 4-methyl-2-phenyl- and 2-acetyl-4-methyldiazaphospholes with the participation of diphenyldiazomethane

✍ Scribed by B. A. Arbuzov; É. N. Dianova


Book ID
112487490
Publisher
Springer
Year
1977
Tongue
English
Weight
58 KB
Volume
26
Category
Article
ISSN
1573-9171

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Photolysis of an antbra&um salt. 5-m~yl-3-N-re~~-~~l-2,l-benzisoxazolium tetratYwobomte (la) gives the we nitrenium ion 2a. Under dir& pbotolysis of la, in the presents of m&ophiles (i.e. ROH), quinone imii ethers such tta (6) are the major product. Triplet gensitized . uradSongivesbotb6andtheparen