Cycloaddition reactions of 5H,7H-thiazolo[3,4-c] oxazolium-1-oxides with imines
✍ Scribed by Piero Dalla Croce; Raffaella Ferraccioli; Concetta La Rosa
- Book ID
- 103399594
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 449 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0040-4020
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📜 SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
AbstractÐ(5R)-3-Methyl-5-phenyl-5H, 7H-thiazolo[3,4-c]oxazol-4-ium-1-olate was generated in the presence of a range of dipolarophiles. The intermolecular 1,3-dipolar cycloaddition of this mesoionic species led to the synthesis of chiral 1H-pyrrolo[1,2-c]thiazole derivatives 7a, 7b, 8, 14, 18, 19 and
## Abstract Fused tricyclic 7‐phenyl‐5__H__‐thizolo[5,4‐__e__]pyrrolo[1,2‐__a__][1,4]diazepin‐10(9__H__)one (**10**) was prepared by thermolysis of 2‐phenyl‐4‐(1‐pyrrolylmethyl)thiazole‐5‐carbonyl azide (**9**) in acetic acid. In addition, starting from **10**, 7‐phenyl‐5__H__‐thiazolo [5,4‐__e__][