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Cycloaddition Reactions of 1,4-Dihydronaphthalene-1,4-epoxide with Cyclohexadiene and 7-(Methoxycarbonyl)cycloheptatriene: Selectivity in Additions

✍ Scribed by Abdullah Menzek; Aliye Altundaş; Ufuk Çoruh; Nihat Akbulut; Ezequiel M. Vázquez López; Tuncer Hökelek; Ahmet Erdönmez


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
140 KB
Volume
2004
Category
Article
ISSN
1434-193X

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## Abstract An (__E__)/(__Z)__ mixture (3 : 2) of 7‐benzylidenecycloocta‐1,3,5‐triene (**5**) is obtained when 1‐benzylcycloocta‐1,3,5,7‐tetraene (**7**), prepared by an improved procedure, is treated with __t__‐BuOK in THF. Alternatively, a __ca.__ 9 : 1 mixture (__E__)/(__Z__)‐**5** can be prepar