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Cycloaddition of (phenylsulfonyl)-1,2-propadienes with diazomethane. Novel rearrangement reactions of the resulting cycloadducts

✍ Scribed by Padwa, Albert; Filipkowski, Michelle A.; Kline, Donald N.; Murphree, S. Shaun; Yeske, Philip E.


Book ID
126981579
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
916 KB
Volume
58
Category
Article
ISSN
0022-3263

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## Abstract Carbenes generated by metal‐catalyzed decomposition of diazo compounds 2 undergo a smooth cycloaddition to the Cο£ΎS bond of thioketenes 1; products 3 were characterized by spectroscopic means as well as an X‐ray structural investigation of 3b. However, photolytic generation of diphenylca