✦ LIBER ✦

Cycloaddition of nitrile oxides to cyclic and acyclic α,β-unsaturated amides. Frontier orbital interactions and an unexpected steric drift determine regiochemistry

✍ Scribed by Pierluigi Caramella; Daniela Reami; Mario Falzoni; Paolo Quadrelli

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 891 KB
Volume: 55
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(99)00331-2

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

ChemInform Abstract: Cycloaddition of Ni

ChemInform Abstract: Cycloaddition of Nitrile Oxides to Cyclic and Acyclic α,β-Unsaturated Amides. Frontier Orbital Interactions and an Unexpected Steric Drift Determine Regiochemistry.

✍ Pierluigi Caramella; Daniela Reami; Mario Falzoni; Paolo Quadrelli 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 40 KB

Cycloadditions of Nitrile Oxides to α,β-

Cycloadditions of Nitrile Oxides to α,β-Unsaturated Aldehydes. Frontier Orbital Interactions and Secondary Orbital Interactions at Work in Determining Regiochemistry

✍ Lucio Toma; Paolo Quadrelli; Giancarlo Perrini; Remo Gandolfi; Cristiana Di Vale 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 195 KB

AbstractÐThe regiochemistry of the cycloadditions of nitrile oxides to crotonaldehyde and cinnamaldehyde has been determined and is dictated by frontier orbital interactions and secondary orbital interactions as well. In cycloadditions to a,b-unsaturated compounds the directive effect of the frontie