Cycloaddition of Isocyanates and Isothiocyanates to Amidines and Guanidines
β Scribed by Dr. H. Ulrich; B. Tucker; Dr. A. A. R. Sayigh
- Publisher
- John Wiley and Sons
- Year
- 1968
- Tongue
- English
- Weight
- 221 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
β¦ Synopsis
N-(2-Hydroxyethyl)-4-nitrobenzenesulfonamide ( 1 ) reacts when heated with an excess of dilute sodium hydroxide solution to give 2-hydroxyethyl-4-nitrophenylamine (2). O z N ~S 0 2 N H -C H z C H 2 0 H -+ 2 NaOH ( 1) (Z), 96% Starting material Rearrangement prod! M.P. ("C
π SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
Oxidation of Isothiocyanates to Isocyanates Using Dimethyldioxirane; Relevance to Biological Activity of Isothiocyanates. -Oxidation of both alkyl and aryl isothiocyanates with dimethyldioxirane affords efficiently the corresponding isocyanates (II), which are trapped with iPrNH 2 to furnish the ur