𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Cycloaddition of Isocyanates and Isothiocyanates to Amidines and Guanidines

✍ Scribed by Dr. H. Ulrich; B. Tucker; Dr. A. A. R. Sayigh


Publisher
John Wiley and Sons
Year
1968
Tongue
English
Weight
221 KB
Volume
7
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.

✦ Synopsis


N-(2-Hydroxyethyl)-4-nitrobenzenesulfonamide ( 1 ) reacts when heated with an excess of dilute sodium hydroxide solution to give 2-hydroxyethyl-4-nitrophenylamine (2). O z N ~S 0 2 N H -C H z C H 2 0 H -+ 2 NaOH ( 1) (Z), 96% Starting material Rearrangement prod! M.P. ("C


πŸ“œ SIMILAR VOLUMES


ChemInform Abstract: Oxidation of Isothi
✍ N. E. DAVIDSON; N. P. BOTTING πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 31 KB πŸ‘ 1 views

Oxidation of Isothiocyanates to Isocyanates Using Dimethyldioxirane; Relevance to Biological Activity of Isothiocyanates. -Oxidation of both alkyl and aryl isothiocyanates with dimethyldioxirane affords efficiently the corresponding isocyanates (II), which are trapped with iPrNH 2 to furnish the ur