𝔖 Bobbio Scriptorium
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Cycloaddition of azides to hexamethyl (Dewar benzene)

✍ Scribed by Paquette, Leo A.; Haluska, Robert J.; Short, Michael R.; Read, Leonard K.; Clardy, Jon


Book ID
127380761
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
770 KB
Volume
94
Category
Article
ISSN
0002-7863

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## Abstract The reactions of 1‐azido‐2,4,6‐trimethyl‐ and 1‐azido‐2,6‐dimethylbenzene with hexamethyl‐__Dewar__‐benzene (HMDB) give rise to the pentamethyl(iminoethyl)‐4__H__‐1,2‐diazepines **4** and **5**, respectively. The X‐ray crystal‐structure analysis of **5** unequivocally established these