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Cyclo[-His-His-] Derived C2-Symmetric Diketopiperazine as Chiral Ligand for Asymmetric Diels-Alder Reactions

โœ Scribed by Kudo, Kazuaki; Furutani, Masahiro; Sakamoto, Seiji

Book ID
125485704
Publisher
Japan Institute of Heterocyclic Chemistry
Year
2009
Tongue
English
Weight
313 KB
Volume
78
Category
Article
ISSN
0385-5414

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C2-Symmetric bipyrrolidines as organocat
C2-Symmetric bipyrrolidines as organocatalysts for asymmetric Dielsโ€“Alder reactions
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A new class of C 2 -symmetric 3,3 0 -dialkoxy-2,2 0 -bipyrrolidines have been designed and developed for asymmetric organocatalytic Diels-Alder reactions of a,b-unsaturated aldehydes. The bipyrrolidines combined with HClO 4 were found to be effective organocatalysts for enantioselective Diels-Alder