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Cyclo- and hydrodimerization of α,β-unsaturated ketones promoted by samarium diiodide

✍ Scribed by Cabrera, Armando; Le Lagadec, Ronan; Sharma, Pankaj; Arias, José Luis; Toscano, Rubén Alfredo; Velasco, Luis; Gaviño, Rubén; Alvarez, Cecilio; Salmón, Manuel

Book ID
118744404
Publisher
Royal Society of Chemistry
Year
1998
Weight
362 KB
Volume
21
Category
Article
ISSN
1472-7781

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## Abstract The ^1^H and ^13^C NMR chemical shift assignments of hydroxycyclopentylpropenone derivatives, prepared by a highly selective reaction between samarium(II) iodide and unsaturated ketones, are described. Two‐dimensional shift‐correlated experiments (COSY, HMBC, HMQC, NOESY) were used to a