✦ LIBER ✦
Cyclization versus polymerization in polycondensation reactions under continuous addition of two symmetrical monomers.
✍ Scribed by Jacques Fastrez
- Book ID
- 104227396
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- French
- Weight
- 272 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
The yields of cyclic oligomers formed in the reactions of two symmetrical monomers are calculated as a function of the dilution and the rate constants of the chemical steps. The consequences for the synthetic strategy for large cycles and the information on the conformation of linear oligomers from yields are discussed.