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cyclization to a Five-Membered Ring in the Free-Radical Reaction of Iodoperfluoroalkanes with 1,6-Heptadiene

✍ Scribed by Brace, Neal O.


Book ID
120971839
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
248 KB
Volume
86
Category
Article
ISSN
0002-7863

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A stereoselective method for introducing a C2-unit at the 1 or-and 1 I~-postions of D-glucose and D-mannose, respectively, via a radical cyclization reaction with vinylsilyl group as a temporary connecting tether, was developed. The radical cyclization of D-glucose substrates was effectively facilit