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Cyclitols. VIII. Bromination of epi-Inositol. Synthesis of Conduritol-C 1a,2

โœ Scribed by McCasland, G. E.; Reeves, John M.


Book ID
127307749
Publisher
American Chemical Society
Year
1955
Tongue
English
Weight
371 KB
Volume
77
Category
Article
ISSN
0002-7863

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โœ Claudia Sanfilippo; Angela Patti; Mario Piattelli; Giovanni Nicolosi ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 292 KB

Lypozymeยฎ IM (immobilised lipase from Mucor miehei) catalyses the enantiomeric alcoholysis of tetraacetylconduritol E (\_+)-2 to give enantiopure (lR,2R,3R,4R)-tetrahydroxycyclohex-5-ene, (-)-1, and the unreacted ester (1S,2S,3S,4S)tetraacetyloxycyclohex-5-ene, (+)-2. The latter was transformed by b