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Cyclic voltammetry of methyl- and trimethylsilyl-substituted zirconocene dichlorides

✍ Scribed by Jan Langmaier; Zdeněk Samec; Vojtěch Varga; Michal Horáček; Robert Choukroun; Karel Mach

Book ID
108354793
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
126 KB
Volume
584
Category
Article
ISSN
0022-328X

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✍ Yan-Long Qian; Xin-Rong Qin; Ji-Ling Huang; Albert Sun-Chi Chan; Shou-Shan Chen; 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 292 KB

## Abstract The syntheses of a series of l‐methyl‐3‐aryl‐substituted titanocene and zirconocene dichlorides are reported. These complexes are synthesized by the reaction of 2‐ and 3‐methyl‐6, 6‐dimethylfulvenes (1:4) with aryllithium, followed by the reaction with TiCl~4~·2THF, ZrCl~4~ and (CpTiCl~