Cyclic voltammetry of cryptands and cryptates containing the ferrocene unit
β Scribed by C. Dennis Hall; Sunny Y.F. Chu
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 550 KB
- Volume
- 498
- Category
- Article
- ISSN
- 0022-328X
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π SIMILAR VOLUMES
Condensation of 1,1 -diacetylferrocene with o-azidobenzaldehyde under appropriate conditions leads either to the [5]-ferrocenophane 2 or the bis(azide) 3, as the only reaction products. Compound 2 undergoes an intramolecular aza-Wittig reaction to give the new type of cryptand 4. Bis(azide) 3 is con
## Abstract The NaBr cryptates of five macrobicyclic ligands containing bipyridine (bpy) and phenanthroline (phen) groups, __i.e__, of [bpy.bpy.bpy] **1** [bpy.bpy.phen] **2** [phen.phen.βphen] **3** [2.1.phen] **4** and [2.2.phen] **5**, have been prepared. **1, 2, 4** and **5** have been obtained
## Abstract The synthesis of a ^15^N enriched macrocycle containing the ferrocene unit is descibed, and the ^15^N NMR spectra of the macrocycle and those of its complexes with some metallic cations are reported.
## Abstract The crystal structures of the LiBr complexes of two macrobicyclic ligands, [py.py.bpy]1 and [py.biqi.biqi] 2, have been determined. They confirm the cryptate nature of these species. In 3, the Li^+^ cation is bound in the shallow cavity of a ligand of flattened shape, whereas in 4, it i