Cyclic voltammetric investigations of the reduction of Mo(VI) to Mo(IV) in 1 M sulphuric acid

The different kinetic and mechanistic be

The different kinetic and mechanistic behaviors of molybdenum and tungsten in the reduction of tris(benzene-1,2-dithiolato)Mo(VI) and W(VI) complexes by ascorbic acid in aqueous media

✍ Francisco Pérez-Pla; Elisa Llopis; María Piles 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 386 KB

## Abstract The mono‐electronic reduction of __tris__(benzene‐1,2‐dithiolato)Mo(VI) and W(VI) complexes (ML~3~: M = Mo, W; L = S~2~C~6~H^2−^~4~, S~2~C~6~H~3~CH^2−^~3~) to their anionic forms ML^−^~3~ by L(+)‐ascorbic acid (H~2~A) has been studied in tetrahydrofurane (THF):water and THF:methanol by