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Cyclic oligomers obtained by polymerization of 2,2-dimethyltrimethylene carbonate in the presence of ϵ-caprolactam

✍ Scribed by Helmut Keul; Thomas Vahlenkamp; Hartwig Höcker

Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
237 KB
Volume
28
Category
Article
ISSN
0014-3057

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✦ Synopsis

The reaction of 2,2-dimethyltrimethylene carbonate (DTC) and E-caprolactam (EClam) in toluene with s-BuLi as initiator leads to cyclic oligomers containing one EClam moiety and n DTC units (n = 2-10). A mechanism for the formation of the oligomers is proposed.

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