Cyclic Diynes by Alkyne Metathesis.
β Scribed by Bjoern Hellbach; Rolf Gleiter; Frank Rominger
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 109 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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π SIMILAR VOLUMES
## Abstract The reaction of the AlCl~3~ complex of cyclic diynes (mainly a 14βmembered ring) with dimethyl acetylenedicarboxylate (DMAD) or bis(__tert__βbutylsulfonyl)acetylene (BTSA) and related compounds was investigated. The reaction of the AlCl~3~ complex of cyclotetradecaβ1,8βdiyne (1, __n__ =
## Abstract The metathesis transformations of cyclohexanes and cyclohexenes bearing allylic and/or propargylic ether substituents has been investigated. A range of products containing fused 6,8βbicyclic ring systems resulting from alkene and/or enyne metatheses were obtained using first and second
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