## Abstract The crystal structures for __cis‐__(Ph~2~PCH=CHPPh~2~)(AuI)~2~ and __trans‐__(Ph~2~PCH=CHPPh~2~)(AuI)~2~ are reported. The structure of __cis‐__(Ph~2~PCH=CHPPh~2~)(AuI)~2~ reveals a short intramolecular Au–Au distance of 2.9526(5) Å, while the structure of __trans__‐(Ph~2~PCH=CHPPh~2~)(
✦ LIBER ✦
Cyclic dinuclear gold(I) complexes: The crystal structure of bis-μ-[(diphenylphosphino)(diphenylphosphinoselenoyl)methane]-digold(I) bis(perchlorate)
✍ Scribed by Schmidbaur, Hubert ;Eschenbach, Jennifer Ebner Von ;Kumberger, Otto ;Müller, Gerhard
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1990
- Tongue
- English
- Weight
- 495 KB
- Volume
- 123
- Category
- Article
- ISSN
- 0009-2940
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## Abstract Novel copper(I) mixed‐ligand complexes containing 1,2‐bis(diphenylphosphanyl)benzene (dppbz) and 2,4‐dithiouracil (2,4‐dtucH~2~) ligands have been synthesised by addition of the thione ligand to the dinuclear [Cu(μ‐X)(dppbz)]~2~ intermediate in acetonitrile/methanol or acetone solution.