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Cyclic cooligomerization of butadiene with methyl methaceylate catalyzed by nickel complexes

โœ Scribed by G. A. Tolstikov; O. S. Vostrikova; U. M. Dzhemilev


Book ID
112437717
Publisher
Springer
Year
1975
Tongue
English
Weight
69 KB
Volume
24
Category
Article
ISSN
1573-9171

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Synthesis of new functionalized polyenes
โœ A. ElAmrani; I. Suisse; A. Mortreux; N. Knouzi ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 414 KB

New polyenes are formed in protic media via nickel catalyzed cooligomerization of butadiene with methyl acrylate. High activities are achieved with amino-phosphinite ligands in aprotic solvent. Using a deuterium labeled ligand, the presence of the NH group of the ligand is shown to be the key point