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Cyclic and high polymeric nido-carboranylphosphazenes as ligands for transition metals

✍ Scribed by Allcock, Harry R.; Scopelianos, Angelo G.; Whittle, Robert R.; Tollefson, Norris M.


Book ID
126193885
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
823 KB
Volume
105
Category
Article
ISSN
0002-7863

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Experimental evidence for a strong decrease of intensities in both ligand field and charge transfer spectia with increased metal-ligand distance is presented. It suggests that overlap of charge clouds for metal ion and ligands is a major source of their intensitics. The polarization ratios in noncub