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Cyanoethylation. I. Weakly Basic Catalysts in the Reaction of Acrylonitrile with Active Methylene Compounds 1

✍ Scribed by Adamcik, Joe A.; Miklasiewicz, Edward J.

Book ID: 121506309
Publisher: American Chemical Society
Year: 1963
Tongue: English
Weight: 541 KB
Volume: 28
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo01037a015

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## Abstract The title aldehyde 1 in the presence of ammonia gives the pyridine derivatives 9‐11 respectively with acetylacetone, diethyl malonate and ethyl cyanoacetate, and ethyl (or methyl)‐l‐benzopyrano[4,3‐__b__]pyri‐dine‐3‐carboxylate **22** (or **23**) with ethyl (or methyl) acetoacetate. Ace