Cyanatocopper(II) complexeswith organic ligands. XVI. Structure characterization of CyanatoCopper(II) complexes with halogeno-pyridine ligands in comparison with analogous methyl-pyridine complexes

✍ Scribed by J Kohout; M Hvastijová; J Gažo; M Nádbovrník

• Publisher: Elsevier Science
• Year: 1979
• Tongue: English
• Weight: 573 KB
• Volume: 37
• Category: Article
• ISSN: 0020-1693
• DOI: 10.1016/s0020-1693(00)95548-8

✦ Synopsis

Qanato-copper(IZ) complexes of the type Cu(NCO),L {L = 2-chloro-or 2-bromopyridine) and clr(NCO),L2 (L = 2-chloro-, 3-chloro-, Ibromo-, 3-iodo-. 4_chloro-. or 4-bromopyridine) have been prepared. The results of various physical methods show that Ck(NCO)?L compkxes have distorted fivecoordinated structures with N-bridging NC0 groups, while Ck(NCO),L, complexes, except for Ctr(NCO),-0a-PY12.