cw Two-photon transitions in K2 molecular beams
✍ Scribed by F. Engelke; U. Schühle
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 543 KB
- Volume
- 123
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
We report on the two-photon visible excitation spectra of potassium molecules in a supersonic beam. A dye laser excites K, to different (7s 'X,, 9s 'Es, Sd 'As) Rydberg states. Two-photon transitions are detected by monitoring the resulting (third-photon) ionization. We have made detailed studies, including rotational assignment of 92 such transitions, 'As( v*, J*) + X 'Z,( v" = 0, J"), where the B'II u state forms the intermediate enhancing state.
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A system of four potential wells with two bound electrons is considered. For specific combinations of spatial locations and depths of the wells, the two-electron-one-photon transitions (TEOPTs) can provide the main channel for the spontaneous relaxation of the excited-state configuration into the gr