Cuprous Chloride Accelerated Stille Reactions. A General and Effective Coupling System for Sterically Congested Substrates and for Enantioselective Synthesis

ChemInform Abstract: Cuprous Chloride Ac

ChemInform Abstract: Cuprous Chloride Accelerated Stille Reactions. A General and Effective Coupling System for Sterically Congested Substrates and for Enantioselective Synthesis.

✍ Xiaojun Han; Brian M. Stoltz; E. J. Corey 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB

Cuprous Chloride Accelerated Stille Reactions. A General and Effective Coupling System for Sterically Congested Substrates and for Enantioselective Synthesis. -A new method is developed that utilizes CuCl/LiCl/Pd(0) for the coupling of aryl perfluoroalkanesulfonates, iodides, or bromides with 1-sub