Cuprates as Selective Metalating Reagents for Aromatic Halides
โ Scribed by Prof. Dr. Yoshinori Kondo; Tetsuji Matsudaira; Junko Sato; Naoko Murata; Prof. Dr. Takao Sakamoto
- Book ID
- 101554725
- Publisher
- John Wiley and Sons
- Year
- 1996
- Tongue
- English
- Weight
- 383 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The oxidative addition of aromatic and benzylic halides to activated metallic nickel occurred under mild conditions to give the corresponding dehalogenative coupled products in good yields. Zero-valent, transition metals in the metallic state generally do not undergo smooth oxidative addition of org
Treatment ofOEPNi with PhSeCI or PhSeCI3, yields mono-through tetra-meso-chlorinated products. The reaction ofPhSeCI~with TPPNi likewise gives di-through poly-fl-chlorinated products. When PhSeBr or PhSeBrj is used as the reagent, OEPNi gives brominated products with the loss of an ethyl group, whil