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Cumulene photochemistry: substituent effects on the mechanism of 1,2-cyclononadiene photochemistry

โœ Scribed by Stierman, Thomas J.; Shakespeare, William C.; Johnson, Richard P.

Book ID
121390023
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
694 KB
Volume
55
Category
Article
ISSN
0022-3263

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The light induced ring closure of cycloheptatrienes to bicycle-[3,2,0]-hepta-2,6-dienes is generally directionally specific in those cases where theoretically two bicyclic products may be formed (1). We have recently rationalised this fact in terms of the effect of eubstituents on the dirdction of p