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Cumulene photochemistry: phenyl and hydrogen migration in phenylallene photoreactions

✍ Scribed by Michael W. Klett; Richard P. Johnson

Publisher: Elsevier Science
Year: 1983
Tongue: French
Weight: 203 KB
Volume: 24
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)81971-1

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✦ Synopsis

Photoreactions of tetra-and triphenylallene and 1,3,3-triphenylcyclopropene in hydrocarbon solvents are reported. Intermediacy of vinylcarbenes is supported by independent generation experiments. Although cyclopropene photochemistry has been widely investigated,I isomeric allenes have received scant attention. As part of a comprehensive study of cumulene photoreactions, we have Recent references: (a) H. E.

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